5-Amino-3-methyl-1-phenyl-1H-1,2,4-triazole

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منابع مشابه

5-Amino-3-methyl-1-phenyl-1H-1,2,4-triazole

In the title compound, C(9)H(10)N(4), the phenyl and triazole rings make a dihedral angle of 38.80 (2)°. N-H⋯N hydrogen bonds link the mol-ecules, forming centrosymmetric R(2) (2)(8) rings; these rings are inter-connected through a C(5) chain, building up a zigzag layer parallel to the (100) plane.

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Crystal structure of 4-amino-3-(3-methyl-5-phenyl-1H-pyrazol-1-yl)-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C12H12N6S, the dihedral angles between the central pyrazole ring and the pendant triazole and benzene rings are 68.01 (4) and 59.83 (9)°, respectively. In the crystal, mol-ecules are linked by N-H⋯N and N-H⋯S hydrogen bonds, generating (10-1) sheets.

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4-Amino-3-phenyl-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C(8)H(8)N(4)S, the planar triazole ring forms a dihedral angle of 13.7 (2)° with the phenyl ring. The crystal structure is stabilized by inter-molecular N-H⋯S hydrogen-bond inter-actions, linking the mol-ecules into chains along the a axis.

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5-Methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid

The title compound, C(10)H(9)N(3)O(2), was synthesized from azido-benzene and ethyl acetyl-acetate. A pair of hydrogen bonds [2.617 (2) Å] inter-connects a pair of the carboxyl groups, forming an R(2) (2)(8) inversion dimer, a frequent motif in carboxylic acids. In the title structure, the bonding H atom in the aforementioned O-H⋯O hydrogen bond is significantly shifted towards the acceptor O a...

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Acetylation of methyl 5-amino-1H-[1,2,4]triazole-3-carboxylate.

Acetylation with acetic anhydride of methyl 5-amino-1H-[1,2,4]triazole-3-carboxylate, one of the hetareneamino acids, was studied using HPLC, H NMR, FTIR and GC-MS. The compound has a significantly decreased susceptibility to acetylation compared to 5-amino-1H-[1,2,4]triazole itself. Two isomeric diacetylated products were found.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808005801